When using Cite While You Write in Word a Bibliography or Reference List is produced from the in-text citations you have inserted into your document from the EN library.
You may want to produce an independent or stand alone bibliography, independent of any in-text citations.
You can do this in two ways:
Export as a separate file - In your EndNote library select references and referencing style as above, then select Export from the File menu, or click on the arrow icon above the EndNote reference library. You can now save this as a separate file - choose to save this as a Word, Text, HTML or XML file.
Copy formatted - In your EndNote library select all the references or select required references from which you want to generate a bibliography. Select the referencing style - Tools > Output Styles - then select Copy Formatted Reference from the References menu. You can now paste these copied references into a Word document, in the place you want this list to appear. Note that this list has no field codes and can be edited as a normal Word document.
Video: EndNote 20 Copy Formatted Reference (1:02)